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Seymour/Carraher´s Polymer Chemistry - Carraher, Charles E., Jr.

Seymour/carraher´s Polymer Chemistry

por Carraher, Charles E., Jr.

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Formato: Tapa dura (Hardcover)
Editorial: Taylor & Francis
Año de Edición: 2010/10/15
Tema: SCIENCE / Chemistry / General, TECHNOLOGY & ENGINEERING / Material Science, TECHNOLOGY & ENGINEERING / Textiles & Polymers
Tags: Polymers, Polymerization
Idioma: Inglés
Páginas: 1088
Estado: Nuevo
ISBN: 1439809550
ISBN 13: 9781439809556
Precio: US$ 113,37
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Resumen del libro
Publisher Summary 1
"This new edition of Carraher's Polymer Chemistry maintains the scope and organization of its bestselling predecessors, while fulfilling the ACS-CPT advanced course requirement. Emphasizing the fundamental behavior of polymers in nature reflected in technological developments, it features new chapters on composites, fibers, and naturally occurring polymers in plants and animals. It also highlights nanoscale polymer applications with new sections on drug design, electronics, optical fibers, textiles, and adhesives. Each chapter includes study tips, glossaries, and exercises. This edition also expands listings for lab exercises, polymer structures, trade names, and Internet resources. Professors adopting the text will be aided by a test-bank available for their exclusive use"--Provided by publisher.
 
Publisher Summary 2
"Updated to reflect a growing focus on green chemistry in the scientific community and in compliance with the American Chemical Society's Committee on professional training guidelines, Carraher's polymer chemistry, eighth edition integrates the core areas that contribute to the growth of polymer science. It supplies the basic understanding of polymers essential to the training of science, biomedical, and engineering students. New in the eighth edition: updating of analytical, physical, and special characterization techniques. Increased emphasis on carbon nanotubes, tapes and glues, butyl rubber, polystyrene, polypropylene, polyethylene, poly(ethylene glycols), shear-thickening fluids, photo-chemistry and photophysics, dental materials, and aramids. New sections on copolymers, including fluoroelastomers, nitrile rubbers, acrylonitrile-butadiene-styrene terpolymers, and EPDM rubber. New units on spliceosomes, asphalt, and fly ash and aluminosilicates. Larger focus on the molecular behavior of materials, including nano-scale behavior, nanotechnology, and nanomaterials. Continuing the tradition of providing a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each chapter contain definitions, learning objectives, questions,and additional reading, and case studies are woven into the text fabric. Symbols, trade names, websites, and other useful ancillaries appear in appendices to supplement the text"--Provided by publisher.
 
Publisher Summary 3
This textbook complies with the American Chemical Society's Committee on Professional Training guidelines for an advanced or in-depth course on the basic science and technology of natural and synthetic polymers. Though designed for an introductory graduate course, it can also be used at an advanced undergraduate level; and though designed to provide a foundation for further study by science and engineering majors, it comprehensively surveys all the areas--synthesis, property, application, and characterization--so can serve as the only course on polymers. A glossary, exercises, and a list for further reading are provided for each of the chapters; the final chapter contains solutions. Annotation ©2011 Book News, Inc., Portland, OR (booknews.com)
 


Tabla de Contenidos del libro
Polymer Nomenclature xxiii
How to Study Polymers xxxv
Chapter 1 Introduction to Polymers
1(22)
1.1 History of Polymers
1(8)
1.2 Why Polymers?
9(3)
1.3 Today's Marketplace
12(3)
1.4 Environmental Assessment
15(3)
1.5 Summary
18(5)
Glossary
18(1)
Exercises
19(1)
Additional Reading
20(1)
General Encyclopedias and Dictionaries
21(2)
Chapter 2 Polymer Structure (Morphology)
23(32)
2.1 Stereochemistry of Polymers
24(6)
2.2 Molecular Interactions
30(8)
2.3 Polymer Crystals
38(4)
2.4 Amorphous Bulk State
42(1)
2.5 Polymer Structure-Property Relationships
42(2)
2.6 Cross-Linking
44(3)
2.7 Crystalline and Amorphous Combinations
47(2)
2.8 Summary
49(6)
Glossary
50(1)
Exercises
51(1)
Additional Reading
52(3)
Chapter 3 Molecular Weight of Polymers
55(38)
3.1 Introduction
55(2)
3.2 Solubility
57(4)
3.3 Average Molecular Weight Values
61(4)
3.4 Fractionation of Polydisperse Systems
65(1)
3.5 Chromatography
65(4)
3.6 Colligative Molecular Weights
69(2)
3.6.1 Osmometry
69(2)
3.6.2 End-Group Analysis
71(1)
3.6.3 Eublliometry and Cryometry
71(1)
3.7 Light-Scattering Photometry
71(6)
3.8 Other Techniques
77(2)
3.8.1 Ultracentrifugation
77(2)
3.8.2 Mass Spectrometry
79(1)
3.9 Viscometry
79(7)
3.10 Summary
86(7)
Glossary
87(2)
Exercises
89(1)
Additional Reading
90(3)
Chapter 4 Polycondensation Polymers (Step-Reaction Polymerization)
93(56)
4.1 Comparison between Polymer Type and Kinetics of Polymerization
93(5)
4.2 Introduction
98(1)
4.3 Stepwise Kinetics
98(5)
4.4 Polycondensation Mechanisms
103(2)
4.5 Polyesters
105(5)
4.6 Polycarbonates
110(4)
4.7 Synthetic Polyamides
114(6)
4.8 Polyimides
120(1)
4.9 Polybenzimidazoles and Related Polymers
121(1)
4.10 Polyurethanes and Polyureas
122(3)
4.11 Polysulfides
125(1)
4.12 Polythers and Epoxys
126(5)
4.13 Polysulfones
131(1)
4.14 Poly(Ether Ether Ketone) and Polyketones
131(2)
4.15 Phenolic and Amino Plastics
133(2)
4.16 Furan Resins
135(1)
4.17 Synthetic Routes
135(1)
4.18 Liquid Crystals
136(4)
4.19 Microfibers
140(1)
4.20 General Stepwise Polymerization
141(2)
4.21 Summary
143(6)
Glossary
144(2)
Exercises
146(1)
Additional Reading
147(2)
Chapter 5 Ionic Chain-Reaction and Complex Coordination Polymerization
149(38)
5.1 Chain Growth Polymerization---General
150(1)
5.2 Cationic Polymerization
150(6)
5.3 Anionic Polymerization
156(5)
5.4 Stereoregularity
161(1)
5.5 Polymerization with Complex Coordination Catalysts
161(2)
5.6 Soluble Stereoregulating Catalysis
163(3)
5.7 Polyethylenes
166(6)
5.8 Polypropylene
172(3)
5.9 Polymers from 1, 4-Dienes
175(3)
5.10 Polyisobutylene
178(1)
5.11 Metathesis Reactions
179(1)
5.12 Zwitterionic Reactions
179(1)
5.13 Isomerization Polymerization
180(1)
5.14 Precipitation Polymerization
180(1)
5.15 Summary
181(6)
Glossary
182(1)
Exercises
183(2)
Additional Reading
185(2)
Chapter 6 Free Radical Chain Polymerization (Addition Polymerization)
187(36)
6.1 Initiators for Free Radical Chain Polymerization
187(4)
6.2 Mechanism for Free Radical Chain Polymerization
191(6)
6.3 Chain Transfer
197(3)
6.4 Polymerization Techniques
200(4)
6.5 Fluorine-Containing Polymers
204(4)
6.6 Polystyrene
208(2)
6.7 Poly(Vinyl Chloride)
210(3)
6.8 Poly(Methyl Methacrylate)
213(2)
6.9 Poly(Vinyl Alcohol) and Poly (Vinyl Acetate)
215(1)
6.10 Polyacrylonitrile
216(1)
6.11 Solid-State Irradiation Polymerization
217(1)
6.12 Plasma Polymerizations
218(1)
6.13 Summary
218(5)
Glossary
219(1)
Exercises
220(1)
Additional Reading
221(2)
Chapter 7 Copolymerization
223(34)
7.1 Kinetics of Copolymerization
223(5)
7.2 Q-e Scheme
228(1)
7.3 Commercial Copolymers
229(1)
7.4 Block Copolymers
230(2)
7.5 Graft Copolymers
232(1)
7.6 Elastomers
233(3)
7.7 Thermoplastic Elastomers
236(1)
7.8 Blends
237(4)
7.8.1 Immiscible Blends
238(1)
7.8.2 Miscible Blends
239(2)
7.9 Fluoroelastomers
241(1)
7.10 Nitrile Rubber
241(1)
7.11 Acrylonitrile-Butadiene-Styrene Terpolymers
242(1)
7.12 EPDM Rubber
243(1)
7.13 Networks---General
243(1)
7.14 Polymer Mixtures
244(1)
7.15 Dendrites
245(2)
7.16 Ionomers
247(2)
7.17 Viscosity Modifiers
249(2)
7.18 Summary
251(6)
Glossary
252(1)
Exercises
253(1)
Additional Reading
254(3)
Chapter 8 Composites and Fillers
257(22)
8.1 Fillers
257(2)
8.2 Types of Composites
259(1)
8.3 Long-Fiber Composites---Theory
260(2)
8.4 Fibers and Resins
262(2)
8.5 Long-Fiber Composites---Applications
264(4)
8.6 Nanocomposites
268(2)
8.7 Fabrication
270(2)
8.7.1 Processing of Fiber-Reinforced Composites
271(1)
8.7.2 Structural Composites
271(1)
8.7.3 Laminating
272(1)
8.7.4 Particulate
272(1)
8.8 Metal-Matrix Composites
272(4)
8.9 Summary
276(3)
Glossary
276(1)
Exercises
277(1)
Additional Reading
277(2)
Chapter 9 Naturally Occurring Polymers---Plants
279(42)
9.1 Polysaccharides
280(2)
9.2 Cellulose
282(2)
9.3 Paper
284(2)
9.4 Cellulose-Regenerating Processes
286(2)
9.5 Esters and Ethers of Cellulose
288(4)
9.5.1 Inorganic Esters
288(1)
9.5.2 Organic Esters
288(2)
9.5.3 Organic Ethers
290(2)
9.6 Starch
292(2)
9.7 Homopolysaccharides
294(5)
9.7.1 Fructans
296(1)
9.7.2 Chitin and Chitosan
297(1)
9.7.3 Others
298(1)
9.8 Heteropolysaccharides
299(3)
9.9 Synthetic Rubbers
302(5)
9.10 Naturally Occuring Polyisoprenes
307(3)
9.11 Resins
310(1)
9.12 Balloons
311(1)
9.13 Lignin
312(1)
9.14 Melanins
313(2)
9.15 Asphalt
315(1)
9.16 Summary
315(6)
Glossary
316(1)
Exercises
317(1)
Additional Reading
318(3)
Chapter 10 Naturally Occuring Polymers---Animals
321(60)
10.1 Proteins
322(3)
10.2 Levels of Protein Structure
325(13)
10.2.1 Primary Structure
326(1)
10.2.2 Secondary Structure
326(1)
10.2.3 Keratines
327(2)
10.2.3.1 Silk
329(1)
10.2.3.2 Wool
330(1)
10.2.4 Collagen
331(1)
10.2.5 Elastin
332(1)
10.2.6 Tertiary Structure
332(1)
10.2.7 Globular Proteins
332(2)
10.2.8 Fibrous Proteins
334(1)
10.2.9 Membrane Proteins
335(1)
10.2.10 Quaternary Structure
335(3)
10.3 Nucleic Acids
338(4)
10.4 Flow of Biological Information
342(2)
10.5 RNA Interference
344(2)
10.6 Polymer Structure
346(3)
10.7 Protein Folding
349(2)
10.8 Genetic Engineering
351(3)
10.9 DNA Profiling
354(2)
10.10 Human Genome---General
356(5)
10.11 Chromosomes
361(11)
10.12 Spliceosomes
372(1)
10.13 Proteomics
373(1)
10.14 Protein Site Activity Identification
374(1)
10.15 Summary
375(6)
Glossary
375(3)
Exercises
378(1)
Additional Reading
379(2)
Chapter 11 Organometallic and Inorganic---Organic Polymers
381(24)
11.1 Introduction
381(2)
11.2 Inorganic Reaction Mechanisms
383(1)
11.3 Condensation Organometallic Polymers
384(6)
11.3.1 Polysiloxanes
385(3)
11.3.2 Organotin and Related Condensation Polymers
388(2)
11.4 Coordination Polymers
390(3)
11.4.1 Platinum-Containing Polymers
392(1)
11.5 Addition Polymers
393(6)
11.5.1 Ferrocene-Containing and Related Polymers
395(2)
11.5.2 Polyphosphazenes and Related Polymers
397(1)
11.5.3 Boron-Containing Polymers
398(1)
11.6 Ion-Exchange Resins
399(2)
11.7 Summary
401(4)
Glossary
401(1)
Exercises
401(1)
Additional Reading
402(3)
Chapter 12 Inorganic Polymers
405(44)
12.1 Introduction
405(1)
12.2 Portland Cements
405(3)
12.3 Other Cements
408(1)
12.4 Silicates
408(4)
12.4.1 Network
411(1)
12.4.2 Layer
411(1)
12.4.3 Chain
412(1)
12.5 Silicon Dioxide (Amorphous)
412(3)
12.6 Kinds of Amorphous Glass
415(1)
12.7 Safety Glass
416(2)
12.8 Lenses
418(2)
12.9 Sol-Gel
420(1)
12.10 Aerogels
421(2)
12.11 Silicon Dioxide (Crystalline Forms)---Quartz Forms
423(1)
12.12 Silicon Dioxide in Electronic Chips
424(1)
12.13 Silicon Dioxide in Optical Fibers
425(1)
12.14 Asbestos
426(1)
12.15 Fly Ash and Aluminosilicates
427(2)
12.16 Polymeric Carbon---Diamond
429(1)
12.17 Polymeric Carbon---Graphite
429(2)
12.18 Internal Cyclization---Carbon Fibers and Related Materials
431(1)
12.19 Carbon Nanotubes
432(6)
12.19.1 Structures
433(5)
12.20 Bitumens
438(1)
12.21 Carbon Black
439(1)
12.22 Polysulfur
440(1)
12.23 Ceramics
441(2)
12.24 High-Temperature Superconductors
443(1)
12.24.1 Discovery of the 123-Compound
443(1)
12.24.2 Structur of the 123-Compound
443(1)
12.25 Zeolites
443(2)
12.26 Summary
445(4)
Glossary
446(1)
Exercises
447(1)
Additional Reading
448(1)
Chapter 13 Testing and Spectrometric Characterization of Polymers
449(34)
13.1 Spectronic Characterization of Polymers
450(4)
13.1.1 Infrared Spectroscopy
450(1)
13.1.2 Raman Spectroscopy
451(1)
13.1.3 NMR Spectroscopy
451(2)
13.1.4 NMR Applications
453(1)
13.1.5 Electron Paramagnetic Resonance Spectroscopy
454(1)
13.1.6 X-Ray Spectroscopy
454(1)
13.2 Surface Characterization
454(5)
13.2.1 Auger Electron Spectroscopy and X-Ray Photoelectron Spectroscopy
455(1)
13.2.2 Near-Field Scanning Optical Microscopy
455(1)
13.2.3 Electron Microscopy
456(1)
13.2.4 SPM
456(3)
13.2.5 Secondary Ion Mass Spectroscopy
459(1)
13.3 Amorphous Region Determinations
459(1)
13.4 Mass Spectrometry
460(1)
13.5 Thermal Analysis
461(2)
13.6 Thermal Property Tests
463(3)
13.6.1 Softening Range
463(1)
13.6.2 Heat Deflection Temperature
463(1)
13.6.3 Glass Transition Temperatures
464(1)
13.6.4 Thermal Conductivity
465(1)
13.6.5 Thermal Expansion
466(1)
13.7 Flammability
466(1)
13.8 Electrical Properties: Theory
466(3)
13.9 Electric Measurements
469(3)
13.9.1 Dielectric Constant
469(1)
13.9.2 Electrical Resistance
470(1)
13.9.3 Dissipation Factor and Power Loss
470(1)
13.9.4 Electrical Conductivity and Dielectric Strength
470(2)
13.10 Optical Properties Tests
472(1)
13.10.1 Index of Refraction
472(1)
13.10.2 Optical Clarity
473(1)
13.10.3 Absorption and Reflectance
473(1)
13.11 Weatherability
473(1)
13.12 Chemical Resistance
474(1)
13.13 Measurement of Particle Size
475(1)
13.14 Measurement of Adhesion
476(1)
13.15 Permeability and Diffusion
477(1)
13.16 Summary
478(5)
Glossary
479(1)
Exercises
480(1)
Additional Reading
480(3)
Chapter 14 Rheology and Physical Tests
483(24)
14.1 Rheology
483(6)
14.1.1 Rheology and Physical Tests
486(3)
14.1.2 Response Time
489(1)
14.2 Typical Stress-Strain Behavior
489(3)
14.3 Stress-Strain Relationships
492(2)
14.4 Specific Physical Tests
494(8)
14.4.1 Tensile Strength
494(2)
14.4.2 Tensile Strength of Inorganic and Metallic Fibers and Whiskers
496(1)
14.4.3 Compressive Strength
497(1)
14.4.4 Impact Strength
497(2)
14.4.5 Hardness
499(1)
14.4.5.1 Brinell Hardness
499(1)
14.4.5.2 Rockwell Hardness
499(2)
14.4.6 Shear Strength
501(1)
14.4.7 Abrasion Resistance
501(1)
14.4.8 Failure
501(1)
14.5 Summary
502(5)
Glossary
503(1)
Exercises
504(1)
Additional Reading
504(3)
Chapter 15 Additives
507(14)
15.1 Plasticizers
507(4)
15.2 Antioxidants
511(1)
15.3 Heat Stabilizers
512(1)
15.4 UV Stabilizers
513(1)
15.5 Flame Retardants
513(2)
15.6 Colorants
515(1)
15.7 Curing Agents
515(1)
15.8 Antistatic Agents---Antistats
516(1)
15.9 Chemical Blowing Agents
516(1)
15.10 Compatibilizers
517(1)
15.11 Impact Modifiers
517(1)
15.12 Processing Aids
517(1)
15.13 Lubricants
517(1)
15.14 Microorganism Inhibitors
517(1)
15.15 Summary
518(3)
Glossary
518(1)
Exercises
519(1)
Additional Reading
520(1)
Chapter 16 Reactions on Polymers
521(32)
16.1 Reactions with Polyolefines and Polyenes
521(1)
16.2 Reactions of Aromatic and Aliphatic Pendant Groups
522(1)
16.3 Degradation
523(2)
16.4 Cross-Linking
525(2)
16.5 Reactivities of End Groups
527(1)
16.6 Supramolecules and Self-Assembly
528(7)
16.7 Transfer and Retention of Oxygen
535(3)
16.8 Nature's Macromolecular Catalysts
538(5)
16.9 Photosynthesis
543(3)
16.9.1 Purple Photosynthetic Bacteria
544(1)
16.9.2 Green Sulfur Bacteria
545(1)
16.10 Mechanisms of Physical Energy Absorption
546(2)
16.11 Breakage of Polymeric Materials
548(1)
16.12 Summary
549(4)
Glossary
550(1)
Exercises
550(1)
Additional Reading
551(2)
Chapter 17 Synthesis of Reactants and Intermediates for Polymers
553(20)
17.1 Monomer Synthesis from Basic Feedstocks
553(5)
17.2 Reactants for Step-Reaction Polymerization
558(6)
17.3 Synthesis of Vinyl Monomers
564(5)
17.4 Synthesis of Free Radical Initiators
569(2)
17.5 Summary
571(2)
Glossary
571(1)
Exercises
571(1)
Additional Reading
572(1)
Chapter 18 Polymer Technology
573(40)
18.1 Polymer Processing
573(2)
18.2 Secondary Structures---Mesophases
575(1)
18.3 Fibers
576(5)
18.3.1 Polymer Processing---Spinning and Fiber Production
576(1)
18.3.1.1 Introduction
576(1)
18.3.2 Melt Spinning
577(2)
18.3.3 Dry Spinning
579(1)
18.3.4 Wet Spinning
579(1)
18.3.5 Other Spinning Processes
580(1)
18.4 Nonspinning Fiber Production
581(1)
18.4.1 Natural Fibers
581(1)
18.5 Elastomers
582(2)
18.5.1 Elastomer Processing
582(2)
18.6 Films and Sheets
584(2)
18.6.1 Calendering
585(1)
18.7 Polymeric Foams
586(1)
18.8 Reinforced Plastics (Composites) and Laminates
586(4)
18.8.1 Composites
586(1)
18.8.1.1 Particle-Reinforced Composites---Large-Particle Composites
587(1)
18.8.1.2 Fiber-Reinforced Composites
588(1)
18.8.1.3 Processing of Fiber-Reinforced Composites
588(1)
18.8.1.4 Structural Composites
589(1)
18.8.2 Laminating
589(1)
18.9 Molding
590(8)
18.9.1 Injection Molding
590(2)
18.9.2 Blow Molding
592(2)
18.9.3 Rotational Molding
594(1)
18.9.4 Compression and Transfer Molding
594(2)
18.9.5 Thermoforming
596(2)
18.10 Casting
598(1)
18.11 Extrusion
598(1)
18.12 Coatings
599(4)
18.12.1 Processing
601(2)
18.12.1.1 Rainwear
603(1)
18.13 Adhesives
603(5)
18.14 Summary
608(5)
Glossary
609(1)
Exercises
610(1)
Additional Reading
611(2)
Chapter 19 Selected Topics
613(54)
19.1 Conductive Polymeric Materials
613(8)
19.1.1 Photoconductive and Photonic Polymers
613(1)
19.1.2 Electrically Conductive Polymers
614(6)
19.1.3 Nanowires
620(1)
19.2 Nonlinear Optical Behavior
621(1)
19.3 Photophysics and Photochemistry---Basics
622(6)
19.4 Drug Design and Activity
628(2)
19.5 Synthetic Biomedical Polymers
630(6)
19.5.1 Dentistry
634(2)
19.6 Sutures
636(5)
19.7 Geotextiles
641(1)
19.8 Smart Materials
642(1)
19.9 High-Performance Thermoplastics
643(2)
19.10 Construction and Building
645(2)
19.11 Flame-Resistant Textiles
647(1)
19.12 Water-Soluble Polymers
648(1)
19.13 Anaerobic Adhesives
649(3)
19.14 Hydrogels
652(1)
19.15 Emerging Polymers
652(5)
19.16 Green Materials
657(4)
19.17 New Materials---Additional Aspects
661(2)
19.18 Summary
663(4)
Glossary
664(1)
Exercises
664(1)
Additional Reading
665(2)
Chapter 20 Solutions
667(26)
Appendix A Symbols
693(6)
Appendix B Trade Names
699(30)
Appendix C Syllabus
729(2)
Appendix D Polymer Core Course Committees
731(2)
Appendix E Structures of Common Polymers
733(6)
Appendix F Mathematical Values and Units
739(4)
Appendix G Comments on Health
743(2)
G.1 Fire
743(1)
G.2 Measures of Toxicity
743(1)
G.3 Cumulative Effects
743(1)
G.4 Environment
744(1)
Appendix H ISO 9000 and 14000
745(2)
Appendix I Electronic Education Web Sites
747(2)
Appendix J Stereogeometry of Polymers
749(8)
Appendix K Statistical Treatment of Measurements
757(2)
Appendix L Combinatorial Chemistry
759(2)
Appendix M Polymerization Reactors
761(4)
M.1 Batch
761(1)
M.2 Plug Flow (Tubular)
762(1)
M.3 Continuous Stirred Tank Reactor
762(3)
Appendix N Material Selection Charts
765(2)
Index 767


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Macromolecules Containing Metal And Metal-like Elements de Abd-el-aziz, Alaa S. (edt)/ Carraher, Charles E., Jr. (edt)/ Pittman, Charles U., Jr. (edt)/ Zeldin, Martel (edt)


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